Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 81, Pages 12040-12042Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06132b
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Funding
- Australian Research Council
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N,S-Dimethyldithiocarbamyl oxalates (e.g. 6, 10) are novel, readily prepared precursors to alkyloxyacyl radicals 1 that are more suitable for kinetic studies than existing precursors; 10 has allowed the determination of accurate rate data for the cyclization of the butenyloxyacyl radical 5 (k(c) = 1.2 x 10(7) s(-1) at 21 degrees C).
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