Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 66, Pages 9302-9305Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03415e
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Funding
- Pennsylvania State University
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Z-Enediynes are prepared by a vicinal dialkynylation of triaryl(arylethynyl)phosphonium cations. The method, which proceeds under mild transition metal-free conditions, can be conducted on multigram scale as a one-pot, phosphine-mediated synthetic cycle giving enediyne products with excellent control of configuration.
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