4.7 Article

Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 28, Pages 3738-3740

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00672k

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Funding

  1. National Science Foundation [CHE-0847358]
  2. 3M Corporation for a Nontenured Faculty Award
  3. Department of Education for GAANN Fellowships
  4. UC Davis for Bradford Borge Chemistry Fellowships
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [0847358] Funding Source: National Science Foundation

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X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)(2), with bifunctional heterocycles for supramolecular assembly. Diffusionordered spectroscopy (DOSY) studies identify the dominant hydrogen-bonding patterns and structures in solution, which correlate with solid-state patterns at high concentrations.

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