4.7 Article

Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 16, Pages 1980-1982

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47769j

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Funding

  1. Deutsche Forschungsgemeinschaft

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A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate product.

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