Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 73, Pages 10604-10607Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04579c
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Funding
- Swiss National Science Foundation
- European Union [PIEF-GA-2010-275400]
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Straightforward deprotonation of soluble tetramethylammonium salts with alkyllithium reagents gives lithiomethyl trimethylammonium reagents. Coordination of the Li cation is crucial to the stability of these 'N-C ylides'. These reagents were used to prepare epoxides, aziridines and allylic alcohols.
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