Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 74, Pages 10861-10863Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04505j
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Funding
- ACCEL project from the Japan Science and Technology Agency
- Japan Society of the Promotion of Science [25000007]
- KAKENHI
- Grants-in-Aid for Scientific Research [13F03032, 25000007] Funding Source: KAKEN
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A perfluorobutyl-functionalized two-dimensional porous coordination polymer (PCP), {[Cu(bpbtp)(L)(DMF)]center dot(DMF)}(n) (H(2)bpbtp = 2,5-bis(perfluorobutyl) terephthalic acid, L = 2,5-bis(perfluorobutyl)-1,4-bis(4-pyridyl)benzene, DMF = N, N-dimethylformamide) has been synthesized and structurally characterized. The pore surface of the PCP is decorated with pendant perfluorobutyl groups which fabricate a densely fluorinated nanospace resulting in unique gas sorption properties.
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