Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 40, Pages 5333-5335Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46396f
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A cubic metal-organic framework with an unprecedented octanuclear secondary building unit (SBU) was isolated. The obtained SBU is composed of 8 Co-II ions at each vertex, 6 mu(4)-OH groups at each face, and 12 cpt(-) ligands framing the metal core. The cuboctahedra arrange in a ubt framework topology, eliciting a highly symmetrical MOF structure. Magnetic measurements as well as DFT calculations on this crystalline MOF reveal intramolecular anti-ferromagnetic coupling between Co-II ions in the octanuclear SBU.
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