4.7 Article

Fluoride free synthesis of anatase TiO2 nanocrystals with exposed active {001} facets

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 78, Pages 11529-11532

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05456c

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Funding

  1. DST, India [SR/S1/IC-33/2011]
  2. CSIR, India, for a SRF fellowship

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A novel fluoride free protocol for highly truncated anatase TiO2 nanocrystals with exposed {001} facets by preferential adsorption of CO32- ions is developed. Experimental observations were corroborated by first principle quantum chemical DFT calculations. The synthesized anatase TiO2 showed improved photocatalytic activity.

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