4.7 Article

Supramolecular self-assembly of three-dimensional polyaniline and polypyrrole crystals

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 84, Pages 12757-12760

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05559d

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Funding

  1. National Natural Science Foundation of China [91022032, 21173001, 21371003]
  2. Anhui Province Key Laboratory of Environment-Friendly Polymer Materials

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Herein, we first report a novel approach for preparing 3D pi-pi stacked crystals of polyaniline and polypyrrole and show how they self-assemble in a suitable solution environment. 3D crystals of polyaniline and polypyrrole show high charge-transport properties of 130 S cm(-1) and 150 S cm(-1), respectively. Remarkably, the 3D crystals of polyaniline obtain excellent anisotropic conductivity.

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