4.7 Article

Electrochemical discrimination of phthalic acid among three phthalic acid isomers based on an N-butylaminomethyl-ferrocene derivative

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 57, Pages 7670-7672

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01659a

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Funding

  1. National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [2012R1A1A1014408, 2013R1A1A2006777]
  2. Fundamental R&D Program for Core Technology of Materials of the Ministry of Knowledge Economy of Korea
  3. Agency for Defense Development through Chemical and Biological Defense Research Center
  4. National Research Foundation of Korea [2013R1A1A2006777, 2012R1A1A1014408] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A chemosensor compound (1) consisting of a central ferrocene with two butylaminomethyl arms showed unexpected facile electrochemical oxidation of the secondary amines in proximity to the ferrocene, which was utilized for electrochemical discrimination of phthalic acid selectively over two other isomers, isophthalic acid and terephthalic acid.

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