4.7 Article

Enantiopure pillar[5]arene active domains within a homochiral metal-organic framework

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 56, Pages 7455-7458

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02559h

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Funding

  1. Joint Center of Excellence in Integrated Nano-Systems (JCIN) at the King Abdul-Aziz City of Science and Technology (KACST) [34-943]
  2. Northwestern University (NU)
  3. KACST
  4. NU
  5. Graduate Research Fellowship from the National Science Foundation [DGE-0824162]

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Enantiopure struts containing pillar[5]arenes incorporating planar chirality have been linked together with Zn4O clusters in order to create metal-organic frameworks that include homochiral active domains and so have the potential to act as a solid support in chiral chromatography.

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