Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 51, Pages 6758-6761Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02567a
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Funding
- U.S. National Science Foundation [CHE-1057904]
- Robert A. Welch Foundation [F-1018]
- National Research Foundation - MEST of Korea [2010-0029668]
- Villum Foundation
- Danish Natural Science Research Council (FNU) [11-106744]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1057904] Funding Source: National Science Foundation
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A pi-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched on-off-on'' emissive system.
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