4.7 Article

Efficient syntheses of pillar[6] arene-based hetero[4]rotaxanes using a cooperative capture strategy

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 47, Pages 6196-6199

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00733f

Keywords

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Funding

  1. Joint Center of Excellence in Integrated Nano-System (JCIN) at the King Abdul-Aziz City of Science and Technology (KACST) [34-943]
  2. Joint Center of Excellence in Integrated Nano-System (JCIN) at Northwestern University (NU) [34-943]
  3. Royal Society, UK
  4. NNSFC [21272093]
  5. SKLSSM

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While a single pillar[6] arene ring, nestling between two cucurbit[6]uril rings in a series of three hetero[4]rotaxanes, is conformationally mobile in solution, it adopts the energetically most favourable conformation with local C-3V symmetry in the solid state.

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