4.7 Article

A cubic dipole lattice of water molecules trapped inside carbon cages

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 5, Pages 524-526

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46683c

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Funding

  1. Mitsubishi Foundation
  2. Murata Science Foundation
  3. Nagoya City University
  4. Grants-in-Aid for Scientific Research [24790061, 23241032, 22225001, 24655027, 24750050] Funding Source: KAKEN

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We report the crystal structure and dielectric properties of a pure H2O@C-60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

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