4.7 Article

Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 82, Pages 12348-12351

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04950k

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Funding

  1. King Abdullah University of Science and Technology (KAUST)
  2. Saudi Basic Industries Corporation (SABIC)

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A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 degrees C into Zn-methyl. At higher temperatures and with CH4/O-2 or CH4/CO2, it gives methanol and acetic acid respectively.

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