Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 30, Pages 3951-3954Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49463b
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [24102508] Funding Source: KAKEN
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A novel crosslink-forming nucleobase, 2-amino-6-(1-ethylthiovinyl)-purine (ATVP), which is triggered by the oxidation of sulfide to sulfoxide, has been developed. The oxidation of ATVP within the duplex proceeded with H2O2 and FeCl2. We have successfully developed the crosslinking reactions activated by oxidation.
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