4.7 Article

Synthesis, structure and reactivity of group 4 corrole complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 22, Pages 2922-2924

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00037d

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Funding

  1. International Fulbright Science and Technology Fellowship
  2. UC-MEXUS Fellowship

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A series of early transition metal corrole complexes has been prepared via salt metathesis with the corresponding lithium corrole. Their characterization by single crystal X-ray diffraction, NMR, and absorption spectroscopy is described. Organometallic derivatives of the titanium complex were obtained via treatment of 2 with NaCp* or ClMgCH2SiMe3.

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