Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 40, Pages 5270-5272Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47372d
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Funding
- Royal Society
- Leverhulme Trust
- European Research Council
- University of Manchester
- Engineering and Physical Sciences Research Council [1232343] Funding Source: researchfish
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In the presence of B(C6F5)(3) five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H-2 as a by-product making the process catalytic in B(C6F5)(3) but also enabling competitive heteroarene hydrogenation.
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