4.7 Article

A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 1, Pages 103-105

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47370h

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Funding

  1. CNRS
  2. Region Alsace, the Departement du Bas-Rhin
  3. Communaute Urbaine de Strasbourg for a Gutenberg Excellence Chair
  4. DFG
  5. CNRS, the MESR (Paris)
  6. UdS, China Scholarship Council

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A novel N, N'-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PCNHCP ligand for M-2 or linear M-3 ( M = Cu, Ag, Au) arrays with metallophilic interactions.

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