Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 3, Pages 335-337Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47251e
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
- UNC Energy Frontier Research Center (EFRC) for Solar Fuels
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Electrocatalytic reduction of carbon dioxide to carbon monoxide and of water/weak acids to hydrogen by a class of polypyridyl ruthenium complexes both occur by well-defined mechanisms involving common intermediates. Based on available mechanistic insight, conditions have been found for competitive electrocatalytic reduction of CO2-H2O-H2PO4- mixtures by a single metal complex catalyst to give syngas products with the H-2 : CO ratio controllable by controlling the composition of the solutions.
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