Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 61, Pages 8339-8342Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02049a
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Funding
- PREST/JST
- MEXT
- Iketani Science and Technology Foundation
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An efficient hydrosolubilizing reagent for [60]fullerene (C-60) was newly developed with a gamma-cyclodextrin (gamma-CD) derivative having triazole-methoxypyridyl moieties at its 6-hydroxyl positions (PCD). Through solid-state mechanochemical complexation, PCD forms a hydrosoluble inclusion complex of C-60 with a concentration of more than 70 mM. This is approximately 90 times greater than that with non-substituted gamma-CD prepared by the same method.
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