4.7 Article

Enhanced stability and activity with Pd-O junction formation and electronic structure modification of palladium nanoparticles supported on exfoliated montmorillonite for the oxygen reduction reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 50, Pages 6660-6663

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02180k

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Funding

  1. China National 973 Program [2012CB215500, 2012CB720300]
  2. NSFC of China [51272297, 21176327]
  3. Fundamental Research Funds for the Central Universities [CDJZR12228802]

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Palladium has been the focus of recent research on alternative Pt catalysts for the oxygen reduction reaction (ORR). We show that the activity and stability of Pd toward the ORR can be enhanced by Pd-O-oxide covalent bonding when Pd is supported on exfoliated montmorillonite (ex-MMT) nanoplatelets.

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