Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 49, Pages 6526-6529Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00976b
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Funding
- JSPS KAKENHI [25630368, 24246129]
- Grants-in-Aid for Scientific Research [26630410, 26289303, 25630368, 26820352] Funding Source: KAKEN
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The selective synthesis of the [Rh-5(CO)(15)](-) cluster within the PPI dendrimer was successfully demonstrated. The dendrimer-encapsulated [Rh-5(CO)(15)](-) was resistant to decomposition under the catalytic reaction conditions and exhibited extremely high selectivity for the chemo-selective reduction of nitro groups of various nitro aromatics with other reducible groups using CO/H2O as a reductant.
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