Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 66, Pages 9273-9276Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03905j
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Funding
- Basic Science Research [2013R1A1A2018730]
- Basic Research Laboratory [20100019766]
- GPF Programs of the National Research Foundation (NRF) - Ministry of Science, ICT and Future Planning of Korea [2011-0006901]
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The C-H imidation of arenes and heteroarenes has been achieved via visible light induced photocatalysis. In the presence of an iridium(III) photoredox catalyst, the reaction of aromatic substrates with N-chloro-phthalimide furnishes the N-aryl products at room temperature through a nitrogen-centered radical mediated aromatic substitution.
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