Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 97, Pages 15333-15336Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05743k
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Funding
- National Natural Science Foundation of China [21232006]
- National Basic Research Program [2011CB808700]
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A highly regio- and stereoselective (up to 99/1) nitro-oxoamination reaction of mono-substituted allene occurs under mild conditions with readily available AgNO2 and a free radical trap TEMPO to form one C-N bond and one C-O bond in one step. Various functional groups and heterocycles could be tolerated in this conversion.
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