Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 25, Pages 3344-3346Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49524h
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Funding
- Japan Society for Promotion of Science (JSPS) [23245020]
- World Premier International Research Center Initiative (WPI), MEXT, Japan
- China Scholarship Council (CSC)
- Grants-in-Aid for Scientific Research [23245020, 25286012, 24106702] Funding Source: KAKEN
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The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arisemainly from the nanoporous structure and the synergistic effect of the AuPd alloy.
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