4.7 Article

Amine-based solvents for exfoliating graphite to graphene outperform the dispersing capacity of N-methyl-pyrrolidone and surfactants

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 72, Pages 10382-10385

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03923h

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Funding

  1. Cluster of Excellence RESOLV - Deutsche Forschungsgemeinschaft (DFG) [EXC 1069]

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Four organic amine-based solvents were discovered which enable direct exfoliation of graphite to produce high-quality and oxygen-free graphene nanosheets. These solvents outperform previously used solvents and additives such as N-methyl-pyrrolidone and surfactants in terms of their dispersing capacity. The resulting dispersions allow the facile fabrication of zeolitic imidazolate framework (ZIF)-graphene nanocomposites with remarkable CO2 storage capability.

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