Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 35, Pages 4554-4557Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49338e
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Funding
- CREST from JST
- NEXT Program
- Program for Leading Graduate Schools Integrative Graduate Education and Research Programin Green Natural Sciences in Nagoya University
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [13J08326] Funding Source: KAKEN
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The first highly E- and enantioselective allylic alkylation of prochiral carbon nucleophiles with 1,2-disubstituted allylic carbonates is reported. The key to the successful development of this protocol is the ability of modular ion-paired chiral ligands to simultaneously control the E/Z selectivity and enantioselectivity.
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