Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 61, Pages 8287-8290Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02415j
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (Japan)
- Chiba University Iodine Research Project
- Workshop on Chirality in Chiba University (WCCU)
- Grants-in-Aid for Scientific Research [25620075, 26105706] Funding Source: KAKEN
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A 3,3'-bis(aminoimino)BINOL ligand was newly designed and synthesized for the formation of a trinuclear Zn complex upon reaction with Zn(0Ac)2. Using the harmony of the tri-zinc atoms, 1 mol% Zn3(0Ac)4-3,3'-bis(aminoimino)binaphthoxide catalyzed asymmetric iodolactonization in up to 99.9% ee.
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