Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 25, Pages 3285-3287Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00148f
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Funding
- National Basic Research Program of China [2011-CB808700]
- National Natural Science Foundation of China [21232006]
- Shanghai Municipal Committee of Science and Technology [12JC1-403700]
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A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity.
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