4.7 Article

Enhancement of spin-crossover cooperativity mediated by lone pair-pi interactions and halogen bonding

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 8, Pages 1003-1005

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48334g

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Funding

  1. Ministerio de Economia y Competitividad of Spain [CTQ2011-27929-C02-01, MAT2011-24284]
  2. Office of Science, Office of Basic Energy Sciences of the U. S. Department of Energy [DE-AC02-05CH11231]
  3. ICREA Funding Source: Custom

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Rational ligand design has allowed the generation of a highly cooperative spin-transition iron(II) complex, an unprecedented result in the family of (2,2'-dipyridylamino/s-triazine)-based SCO materials.

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