Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 5, Pages 545-547Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48037b
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A set of three core-cyanated isoindigos was synthesized by palladium-catalyzed cyanation of core-brominated isoindigos. With decreased LUMO level to -3.88 eV, the dicyanated isoindigo 5 showed ambient-stable electron mobility up to 0.044 cm(2) V-1 s(-1) in OTFTs with SAMs of TPA, while it exhibited ambipolar charge transport behaviour (0.11 cm(2) V-1 s(-1) for electrons and 0.045 cm(2) V-1 s(-1) for holes) on FOPA-modified substrates.
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