Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 11, Pages 1326-1329Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48196d
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Funding
- Hungarian National Research Fund [OTKA K108489]
- Hungarian Academy of Sciences through a Janos Bolyai Scholarship (JSP)
- University of Groningen through an Ubbo Emmius Scholorship
- COST Action Biological oxidation reactions-mechanism and design of new catalyst'' [CM1003]
- ERC [279549]
- [TAMOP-4.2.2.A-11/1/KONV-2012-0071]
- [TAMOP-4.2.2/B-10/1-2010-0025]
- European Research Council (ERC) [279549] Funding Source: European Research Council (ERC)
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The spectroscopic characterisation of the (mu-1,2-peroxido) diiron(III) species formed transiently upon reaction of [Fe(II)(NN)(3)](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.
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