Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 11, Pages 1359-1361Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47504b
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Funding
- QOPNA [PEst-C/QUI/UI0062/2013]
- CESAM
- CICECO [Pest C-CTM/LA0011/2013, PTDC/CTM/101538/2008]
- FCT [SFRH/BPD/73060/2010, SFRH/BD/81014/2011, SFRH/BD/51486/2011]
- U.S. National Science Foundation [NSF CHE-1057904]
- Fundação para a Ciência e a Tecnologia [PTDC/CTM/101538/2008, Incentivo/CTM/LA0011/2013] Funding Source: FCT
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New porphyrin-based anion receptors have been prepared from meso-tetrakis(pentafluorophenyl) porphyrin (TPPF20) and diamine derivatives. These receptors (compounds 1-3) interact preferentially with phosphate anions both in organic solutions and in basic aqueous media when coated on gold piezoelectric quartz crystals. A single crystal X-ray structure of the bis-HF complex of a imine derivative of 1 was obtained; it serves to highlight the main interactions between the anion and cation receptors in the solid state.
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