4.7 Article

In situ potential distribution measurement in an all-vanadium flow battery

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 56, Pages 6292-6294

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42092b

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Funding

  1. NSF [0644811]
  2. TN-Score [NSF EPS-1004083]
  3. Directorate For Engineering
  4. Div Of Chem, Bioeng, Env, & Transp Sys [0644811] Funding Source: National Science Foundation

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An experimental method for measurement of local redox potential within multilayer electrodes was developed and applied to all-vanadium redox flow batteries (VRFBs). Through-plane measurement at the positive side reveals several important phenomena including potential distribution, concentration distribution of active species and the pre-dominant reaction location within the porous carbon electrodes.

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