Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 6, Pages 561-563Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37464a
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Funding
- National Science Foundation [NSF 21072080, 21272101]
- National Basic Research Program of China (973 Program) [2010CB833203]
- 111 program of MOE
- Natural Science Foundation of Gansu [096RJZA006]
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Two different cyclic amino esters are synthesized by palladium-catalyzed cross-coupling reaction of diazoesters with N-substituted-2-iodoanilines. Aryldiazoacetates lead to cyclic alpha-amino esters with an alpha-quaternary carbon centre in the presence of CO. Additionally, arylvinyldiazoacetates afford cyclic alpha,beta-unsaturated gamma-amino esters.
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