4.7 Article

Phosphorescence from a pure organic fluorene derivative in solution at room temperature

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 76, Pages 8447-8449

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44809f

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Funding

  1. MEXT (Japan)
  2. JSPS
  3. Grants-in-Aid for Scientific Research [11J08939] Funding Source: KAKEN

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A fluorene derivative having both bromo and formyl groups exhibited bright phosphorescence emission in common organic solvents at room temperature. The absolute phosphorescence quantum yield reached 5.9% in chloroform at 298 K. When the fluorene derivative was incorporated into a poly(methyl methacrylate) film, the phosphorescence emission was similarly observed even under air at room temperature for over five days.

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