4.7 Article

A sodium manganese ferrocyanide thin film for Na-ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 27, Pages 2750-2752

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38839e

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Funding

  1. Mitsubishi foundation
  2. Cannon foundation
  3. Ministry of Education, Culture, Sports, Science and Technology [21244052]

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A thin film of sodium manganese ferrocyanide, Na1.32Mn[Fe(CN) 6](0.83).3.5H(2)O, exhibits discharge capacity (= 109 mA h g(-1)) and discharge voltage (3.4 V in average) at 0.5 C against Na in aprotic solvent. The ex situ XRD experiments reveal that the host framework remains cubic without showing any structural phase transition during the charge process. The discharge property is discernible up to 40 C.

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