4.7 Article

An aggregation-induced emission luminophore with multi-stimuli single- and two-photon fluorescence switching and large two-photon absorption cross section

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 3, Pages 273-275

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36806d

Keywords

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Funding

  1. NSF of China [51173210, 51073177]
  2. Fundamental Research Funds for the Central Universities
  3. NSF of Guangdong [S2011020001190]

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A novel aggregation- and crystallization-induced emission luminophore (ENPOMe) containing tetraphenylethene and acrylonitrile moieties with high fluorescence efficiency (Phi(F) of up to 0.85) has been easily synthesized. ENPOMe has an exceptionally large two-photon absorption cross section (sigma) of 5548 GM, and exhibits striking multi-stimuli-responsive single- and two-photon fluorescence switching with excellent reversibility in the solid state.

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