Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 10, Pages 972-974Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36325a
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For the first time a metal hydride has been used for the preparation of a metal-organic framework. MIL-78 has been synthesized by the solid-state mechanochemical reaction between yttrium hydride and trimesic acid. The process does not involve solvents and does not generate liquid by-products, thus proving the viability of the solid-state approach to the synthesis of MOFs.
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