4.7 Article

Superhydrophobic perfluorinated metal-organic frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 61, Pages 6846-6848

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41564c

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Funding

  1. University of Houston
  2. Norman Hackerman Advanced Research Program
  3. National Science Foundation [CHE-1151292]
  4. American Chemical Society Petroleum Research Fund [50390-DNI10]
  5. Welch Foundation [E-1571, E-1768]
  6. Camille and Henry Dreyfus Foundation
  7. Division Of Chemistry
  8. Direct For Mathematical & Physical Scien [1151292] Funding Source: National Science Foundation

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Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 +/- 1 degrees, they are among the most water-repellent MOFs ever reported.

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