4.7 Article

Facile assembly of an efficient CoOx water oxidation electrocatalyst from Co-containing polyoxotitanate nanocages

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 39, Pages 4331-4333

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34934e

Keywords

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Funding

  1. EPSRC [EP/H00338X/2]
  2. Christian Doppler Research Association (Austrian Federal Ministry of Economy, Family and Youth)
  3. Christian Doppler Research Association (National Foundation for Research, Technology and Development)
  4. OMV Group
  5. Ministry of Education of Taiwan [SAS-100-1-13-2-UK-034]
  6. China Scholarship Council
  7. National Natural Science Foundation of China [NSFC 20973127]
  8. EPSRC
  9. EPSRC [EP/F00253X/1] Funding Source: UKRI
  10. Engineering and Physical Sciences Research Council [EP/F00253X/1, EP/H00338X/2] Funding Source: researchfish

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Cobalt-containing polyoxotitanates (TiCo) are excellent precursors for the simple and scalable preparation of Nocera-type CoOx water-oxidation electrocatalysts. The TiCo cages serve as a reservoir for cobalt ions in a titania matrix on fluoride-doped tin oxide electrodes, and form, in situ, the active CoOx catalyst for O-2 evolution with high stability in phosphate buffer in pH neutral water.

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