Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 16, Pages 1606-1608Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc37695h
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Funding
- US Department of Energy [DE-AR0000177]
- NSF [TG-DMR090028]
- University of South Florida
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Pillar substitution in a long-known metal-organic material with saturated metal centres, [Cu(bipy)(2)(SiF6)](n), has afforded the first crystallographically characterized porous materials based upon TiF62- and SnF62- anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2 vs. CH4 and N-2.
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