4.7 Article

Carborane tuning of photophysical properties of phosphorescent iridium(III) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 42, Pages 4746-4748

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40996a

Keywords

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Funding

  1. National Natural Science Foundation of China [20925104, 21271102, 21021062]
  2. Major State Basic Research Development Program of China [2013CB922100, 2010CB923303, 2009CB930601]

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Both neutral and cationic iridium(III) complexes containing carborane units were synthesized. Bulky carboranes can significantly improve phosphorescence quantum yields of these complexes and the electronic effect of carboranes can evidently tune emission wavelengths of cationic complexes.

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