4.7 Article

Metallic zinc-assisted synthesis of Ti3+ self-doped TiO2 with tunable phase composition and visible-light photocatalytic activity

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 9, Pages 868-870

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37976g

Keywords

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Funding

  1. National Basic Research Program of China [2013CB632401]
  2. National Natural Science Foundation of China [20973102, 51021062, 11174180]
  3. Ministry of Education Academic Award

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Stable Ti3+ self-doped TiO2 with tunable phase composition and highly efficient visible-light photoactivity (ca. 32.7 times stronger than an undoped sample for (OH)-O-center dot formation) was synthesized via a facile metallic zinc-assisted method. The surface Ti3+ species can be stabilized by Zn doping, and the photocatalytic selectivity can be regulated by the phase composition.

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