4.7 Article

A dinuclear ruthenium catalyst with a confined cavity: selectivity in the addition of aliphatic carboxylic acids to phenylacetylene

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 7, Pages 710-712

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc38454j

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Funding

  1. Hong Kong Polytechnic University
  2. Innovation and Technology Commission
  3. Research Grants Council [PolyU 5015/07P]
  4. University Grants Committee [SEG_PolyU01]

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A dinuclear ruthenium catalyst with a rigid anthracene spacer shows excellent regio- and stereo-selectivity in the atom-economic addition of aliphatic carboxylic acids to phenylacetylene, producing exclusively anti-Markovnikov enol-esters with high E/Z ratios of the isomers.

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