4.7 Article

A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 61, Pages 6843-6845

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc00249g

Keywords

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Funding

  1. state key project of Fundamental Research for Nanoscience and Nanotechnology [2011CB93240, 2011CBA00500]
  2. National Natural Science Foundation of China [20921001, 21131004]
  3. Tsinghua-Peking University Joint Centers for Life Sciences
  4. National Key Basic Research Program of China [2012CB224802]

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Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1-xAgx (x = 0-1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

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