Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 85, Pages 9905-9907Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45455j
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The first examples of sigma-coordinated metal-haloboryl complexes have been synthesised. The haloboryl moiety may be functionalized by nucleophilic substitution reactions, by which more electron-withdrawing substituents may be installed at the boron center.
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