Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 89, Pages 10513-10515Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46379f
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Funding
- National Natural Science Foundation of China [21172115, 20972076]
- Research Fund for the Doctoral Program of Higher Education of China [20120031110002]
- Natural Science Foundation of Tianjin [13JCYBJC38700]
- Tianjin Municipal Education Commission [20120502]
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PPh3-Catalyzed aza-MBH domino reaction of salicyl N-tosylimines with gamma-CH3 substituted allenoates is reported. Readily available imines and allenoates are converted to benzoxazepine derivatives in one step. Wherein, functionalization of C-H bonds of gamma-substituted allenoate has been developed in this domino process.
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