Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 20, Pages 2058-2060Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38264h
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Funding
- National Natural Science Foundation of China [21072100, 21272119, 21121002]
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A phosphine-catalyzed [3+2] annulation reaction of alpha-substituted allenoates with ester-activated alpha,beta-unsaturated imines is reported, which provides new and efficient access to highly functionalized cyclopentenes bearing one all-carbon quaternary center. This reaction also expands the scope of the famous Lu [3+2] cycloaddition reaction.
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